How To Calculate Electron Affinity From Born Haber Cycle

How do you calculate second ionization energy using the Born-Haber cycle?

Use the data given below to construct a born-haber cycle to determine the second ionization energy of Ca Step 1: Convert Ca(s) into a gas, Ca(g) Step 2: Convert Ca(g) into its ion, Ca + (g) Step 3 Convert Ca + (g) into its ion, Ca + 2 (g) Step 4: Split ½ O 2 (g) into O(g) atoms Step 5: Convert O(g) into the O – (g) ion

Does electronegativity involved in Born-Haber cycle?

The magnitude of the dissociation energy depends on the electronegativity of the atoms involved Sublimation energy is the energy required to cause a change of phase from solid to gas, bypassing the liquid phase The Born-Haber Cycle is essentially Hess’s Law applied to an ionic solid

How do you find the second electron affinity?

Second Electron Affinity X−(g)+e−→X−2(g) Og+e−→O−(g)1st EA = -142 kJ mol−1 O−g+e−→O2−(g)2nd EA = +844 kJ mol−1

How do you calculate lattice energy using the Born Haber cycle?

The net enthalpy of formation and the first four of the five energies can be determined experimentally, but the lattice energy cannot be measured directly Instead, the lattice energy is calculated by subtracting the other four energies in the Born–Haber cycle from the net enthalpy of formation

What is the electron affinity of CL?

Elements Z Element Electron affinity (eV) 17 Cl 3612 725(28) 18 Ar -10(2) 19 K 0501 459(13) 20 Ca 0024 55(10)

How do you find the heat of formation using the Born Haber cycle?

Born – Haber Cycle Equation Heat of formation= Dissociation Energy + Sublimation Energy + Ionization Energies – Electronic Affinities + Lattice Energy

What is born Haber cycle explain with an example?

Born Haber cycle is a cycle of enthalpy change of process that leads to the formation of a solid crystalline ionic compound from the elemental atoms in their standard state and of the enthalpy of formation of the solid compound such that the net enthalpy becomes zero

How do you find the bond enthalpy of Born Haber cycle?

Born-Haber cycles The bond enthalpy for Cl−Cl bond is greater than Br−Br bond because Cl−Cl bond length is shorter (0199nm vs NB ΔH ⦵ f NH 3 (g) = Σ (breaking bonds) − Σ (forming bonds) = [(½ × 944) + (1½ × 436] − [(388× 3)]= −38 kJ mol − 1

What units of measurement are used for electron affinity?

Definition: The energy released when an electron is added to a gaseous atom which is in its ground state to form a gaseous negative ion is defined as the first electron affinity The symbol is EA, and the unit is kJ/mol

What is the electron affinity of neon?

The electron affinity of neon is 0 kJ mol1

How do you find the electron affinity of chlorine?

Chlorine – Electron Affinity – Electronegativity – Ionization Energy of Chlorine Electron Affinity of Chlorine is 349 kJ/mol Electronegativity of Chlorine is 316 Electron Affinity X + e – → X – + energy Affinity = – ∆H Affinities of Non metals vs Electronegativity

Why is 2nd electron affinity endothermic?

2nd electron affinity is always endothermic (positive) because the electron is added to an ion which is already negative therefore it must overcome the repulsion

Is ionization energy equal to electron affinity?

For a neutral atom, the first ionization energy is equal to its electron affinity

What is electron affinity class 11?

Electron affinity is defined as The amount of energy released when an electron is added to a neutral atom to form an anion The electron affinity is the potential energy change of the atom when an electron is added to a neutral gaseous atom to form a negative ion

What is 2nd ionization energy?

An element’s second ionization energy is the energy required to remove the outermost, or least bound, electron from a 1+ ion of the element Because positive charge binds electrons more strongly, the second ionization energy of an element is always higher than the first

How do you calculate lattice energy using Coulomb’s law?

Lattice energy depends on the strength of interactions between cations and anions in the lattice, which we can estimate using Coulomb’s law: Fₑ = (q₁q₂)/r² According to this equation, stronger interactions occur between ions with larger charges and smaller radii

How does Born Haber cycle explain stability of ionic compound?

Ionic solids tend to be very stable compounds The enthalpies of formation of the ionic molecules cannot alone account for this stability These compounds have an additional stability due to the lattice energy of the solid structure

What is the electron affinity of bromine?

A7: Electron Affinities Z Element Electron affinity (kJ/mol) 35 Br 3245371(3) 36 Kr – 37 Rb 46884(2) 38 Sr 5023(6)

How do you derive born Lande equation?

Born–Landé equation N A = Avogadro constant; M = Madelung constant, relating to the geometry of the crystal; z + = numeric charge number of cation z − = numeric charge number of anion e = elementary charge, 16022×10 − 19 C ε 0 = permittivity of free space 4πε 0 = 1112×10 − 10 C 2 /(J·m) r 0 = distance to closest ion

What is the lattice energy of CsBr?

Representative lattice energies Compound Experimental Lattice Energy Structure type CsBr −632 kJ/mol CsCl CsI −600 kJ/mol CsCl MgO −3795 kJ/mol NaCl CaO −3414 kJ/mol NaCl

What is lattice enthalpy calculated indirectly using Born Haber cycles?

Lattice Enthalpy – The lattice enthalpy of a crystalline solid is a measure of the energy released when the ions are combined to make this compound The lattice enthalpy is indirectly determined by the use of the Born-Haber Cycle This procedure is based on Hess’s law

What is Hess law state?

Hess’s law states that if a process can be expressed as the sum of two or more steps, the enthalpy change for the overall process is the sum of the ΔH values for each step To use Hess’s law, two principles must be understood: one, if an equation is reversed, the sign of the ΔH value is also reversed

How do you calculate lattice?

Calculate the lattice constant, a, of the cubic unit cell If the space lattice is SC, the lattice constant is given by the formula a = [2 x r] For example, the lattice constant of the SC-crystallized polonium is [2 x 0167 nm], or 0334 nm

Which step in the Born Haber cycle will typically be endothermic?

As you can see in the accompanying diagram, the first step involves formation of gaseous sodium metal from solid sodium metal This is called the sublimation energy of sodium, and represented by Hsub This step is endothermic, with sublimation energy of sodium being +108 KJ